Thermodynamics

 

Thermodynamics

01) Relationship between temperature scales




WHERE :


`C = Celsius scale


`F = Fahrenheit Scale


K = Kelvin scale



NOTE : Permanent low temperature is the value at which pure water becomes ice under standard atmospheric pressure ( o’ C , 32’ F , 273 K ) . Permanent high temperature is the value at which pure water becomes steam under standard atmospheric pressure ( 100’ C , 212’ F , 373 K ) .


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02) Triple point of water




WHERE :


T = Temperature required to measure (K)


x = Magnitude of the thermodynamic quality at the temperature required to measure


x(t) = Magnitude of the thermometric quality at the triple point


NOTE : The triple point of water is the temperature at which all the solid, liquid, and gaseous states are in equilibrium.



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03) Linear expansion of solids




WHERE :


ΔL = Difference in length


α = Linear expansion coefficient


L(1) = Startup length


L(2) = Last length


θ(1) = Temperature relative to the starting length


θ(2) = Temperature relative to the last length



NOTE: When an object is heat-increased and its temperature is increased relative to its length, these are called linear expansion.



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04) Area expansion of solids




WHERE :


ΔA = Difference in Area


β = Area expansion coefficient


A(1) = Startup Area


A(2) = Last Area


θ(1) = Temperature relative to the starting Area


θ(2) = Temperature relative to the last Area



NOTE: When an object is heat-increased and its temperature is increased relative to its Area, these are called Area expansion.



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05) Volume expansion of solids




WHERE :


ΔV = Difference in Volume


γ = Volume expansion coefficient


V(1) = Startup Volume


V(2) = Last Volume


θ(1) = Temperature relative to the starting Volume


θ(2) = Temperature relative to the last Volume


NOTE: When an object is heat-increased and its temperature is increased relative to its Volume, these are called Volume expansion.



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06) Relationship between expansion coefficients




WHERE :


α = Linear expansion coefficient


β = Area expansion coefficient


γ = Volume expansion coefficient


NOTE: Since the expansion coefficients are very small, the square is near to zero.


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07) Function of a bi-metal belt




WHERE :


R = Radius when changes temperature of the two-metal band


d(1) = Expansion large metal Thickness


d(2) = Expansion Small metal Thickness


α(1) = Expansion large metal coefficient


α(2) = Expansion Small metal coefficient


θ(1) = Lower temperature


θ(2) = High temperature


NOTE : Two different expansion coefficients of metals are arranged one by one for the operation of a two-metal band.


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08) Error in hanging clocks




WHERE :


T’ = Correct periodic period


T = Displayed periodic period


α = Expansion coefficient


ΔT = Periodic error


θ(1) = Lower temperature


θ(2) = High temperature



NOTE : A periodic clock can cause errors in the periodicity of the suspended clock depending on its temperature.



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09) True expansion of a liquid




WHERE :


∆V(true) = Total volume of the liquid increases


V(1) = First fluid volume


γ(true) = True liquid expansion coefficient


Δθ = Temperature difference



NOTE: True expansion is the full expansion of a liquid, taking into account the expansion of the pot.



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10) Visual expansion of a liquid



WHERE :


∆V(visual) = Volume of boiling liquid


V(1) = First fluid volume


γ(visual) = Visual liquid expansion coefficient


Δθ = Temperature difference



NOTE: It does not take into account the expansion of the pot.



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11) True total expansion of the liquid



WHERE :


∆V(True total) = True total expansion of the liquid


∆V(pot) = Expansion of the pot


∆V(visual) = Visual expansion of the liquid


NOTE: The volume expansion equation must be used to find the expansion of the pot.


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12) Relationship between temperature and density of a liquid




WHERE :


ρ(1) = Density at low temperature


ρ(2) = Density at high temperature


γ(true) = True expansion coefficient


∆θ = Temperature difference


NOTE: When heating a liquid, there is a decrease in the density and when the liquid is cooled the density increases.


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13) Heat capacity




C = m s




WHERE :


C = Heat capacity


m = Mass of the object


s = Specific Heat capacity of the object



NOTE: Heat capacity is the amount of heat that must be supplied or discharged to change the temperature of the object by 1 degree Celsius.



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14) Thermal energy ( which does not change the situation)




Q = C Δθ



Q = m s Δθ




WHERE :


Q = Thermal energy


C = Heat capacity


m = Mass of the object


s = Specific Heat capacity of the object


Δθ = Temperature difference



NOTE: Here solid, liquid, and gaseous phase does not change.



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15) Thermal energy (changes the situation)




Q = m L




WHERE :


Q = Thermal energy


L = Specific latent heat of evaporation


m = Mass that turned into steam



NOTE: Here solid, liquid, and gaseous phase change of matter.



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16) Heat transfer rate




WHERE :


Q / t = Heat transfer rate


L = Specific latent heat of evaporation


m = Mass that turned into steam


M = Mass of the object


s = Specific Heat capacity of the object


Δθ = Temperature difference


t = Time (කාලය)



NOTE: Here we consider how rapidly the temperature change or phase change occurs.



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17) Temperature gradient




WHERE :


G = Temperature gradient


Δθ = Temperature difference


l = Gap



NOTE: Temperature gradient is the temperature difference across units.



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18) Rate of Thermal conduction




WHERE :


Q/t = Rate of Thermal conduction


K = Thermal conductivity coefficient


A = Cross-sectional area of the conductor


l = Distance between the temperature measured points


Δθ = Difference between the temperatures



NOTE : Thermal conductivity coefficient is higher in conductors and lower in non-conductors.


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19) Density



WHERE :


V = Volume


ρ = Density


m = Mass


NOTE: As the volume increases, the density decreases.


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20) Newton's law of cooling



WHERE :


ΔQ/ Δt = Heat Damage Rate


E = Cooling constant


A = Cross-sectional area of Surface


θ = Temperature of the object


θ(r) = Temperature of the environment



NOTE : Newton's law of cooling can be applied to any temperature difference under artificial convection, but under natural convection the additional temperature is about 30 degrees Celsius.



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21) Cooling rate




WHERE :


Δθ/ Δt = Cooling rate


t = Time


θ(1)- θ(2) = Temperature drop



NOTE : As the heat dissipates from any object, its temperature decreases and the temperature drop per unit time is the cooling rate.



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22) Relation between cooling rate and Newton's law of cooling



WHERE :


Δθ/ Δt = Cooling rate


E = Cooling constant


A = Cross-sectional area of Surface


m = Mass of the object


s = Specific Heat capacity of the object


θ(r) = Temperature of the environment


θ = Temperature of the object


NOTE : Here is the relationship between the cooling temperature and the extra temperature of an object that is damaged by convection.



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23) Pressure




WHERE :


P = Pressure


cos⁡θ = Angle to the surface


F = Force perpendicular to the surface


A = Surface area



NOTE: When pressure is measured always must use perpendicular force to the Surface.


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24) Boyle's law



WHERE :


P(1) = First case pressure


P(2) = Second stage pressure


V(1) = First case volume


V(2) = Second case volume


NOTE : The mass and temperature of the gas must be constant for any two instances of Boyle's law.



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25) Charles's law (type 1)



WHERE :


T(1) = First case Temperature


T(2) = Second stage Temperature


V(1) = First case volume


V(2) = Second case volume



NOTE : The mass and pressure of the gas must be constant for any two instances of Charles's law.



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26) Charles's law (type 2)



WHERE :


T(1) = First case Temperature


T(2) = Second stage Temperature


P(1) = First case Pressure


P(2) = Second case Pressure



NOTE : The mass and Volume of the gas must be constant for any two instances of Charles's law.



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27) Gas phase equation



WHERE :


T(1) = First case Temperature


T(2) = Second stage Temperature


P(1) = First case Pressure


P(2) = Second case Pressure


V(1) = First case Volume


V(2) = Second case Volume


NOTE : This equation is used for two stages of gas and in both cases the gas mass must be constant.



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28) Number of moles




WHERE :


n = Number of moles


m = Mass of the gas


M = Molecular mass


N = Number of subsets or atoms


L = Avogadro number



NOTE: This formula is used to find the number of moles.



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29) Perfect gas equation




P V = n R T




WHERE :


n = Number of moles


R = Universal gas constant


T = Temperature


P = Pressure


V = Volume



NOTE: Derivative equations can be obtained by substituting the appropriate formulas for the number of moles or the density of the gas. The universal air constant is 8.314 joules per mole per Kelvin.



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30) Boltzmann gas constant




WHERE :


K = Boltzmann gas constant


R = Universal gas constant


L = Avogadro number



NOTE: These equations are used to obtain derivative equations..


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31) Perfect gas equation with the Boltzmann gas constant




P V = n K T




WHERE :


n = Number of moles


K = Boltzmann gas constant


T = Temperature


P = Pressure


V = Volume



NOTE: Perfect gas equation is derived from the Boltzmann gas constant.



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32) Mass of a gas



WHERE :


m = Mass of a gas


N = Number of subsets or atoms


m``` = Mass of an subset or atom



NOTE: This equation is used to derive equations.


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33) Equation of kinetic theory




WHERE :


m``` = Mass of subsets


N = Number of subsets or atoms


C^2 = Root mean square velocity


P = Pressure


V = Volume In the gas


ρ = Density of the gas


m = Mass of a gas


NOTE : When a particle of gas moves in different directions in closed pot , the total momentum is zero.



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34) Kinetic energy of an air subset




WHERE :


E = Kinetic energy of an air subset


m``` = Mass of subsets


K = Boltzmann gas constant


C^2 = Root mean square velocity


T = Temperature



NOTE : Only kinetic energy of one air subset is obtained here.



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35) Total Kinetic energy of an air subset




WHERE :


E = Kinetic energy of an air subset


m``` = Mass of subsets


K = Boltzmann gas constant


C^2 = Root mean square velocity


T = Temperature


N = Number of subsets or atoms



NOTE : Total kinetic energy of air subsets are obtained here.



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36) Relationship between Root mean square velocity and temperature




WHERE :


R = Universal gas constant


C^2 = Root mean square velocity


T = Temperature


M = Molecular mass



NOTE : These equation is obtained by deriving the air equations.


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37) Heat exchanged in a thermodynamic system



WHERE :


∆Q = Heat exchanged difference in the system


∆u = Internal energy change in the system


∆W = Difference in the work done with the environment


NOTE: This law is the expression of the interplay of heat, internal energy, and work in a gas.



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38) Work done by the pressure of a gas




WHERE :


∆W = Work done by the pressure of a gas


P = Pressure


∆V = Volume difference


NOTE: It describes the work done by changing the volume of a gas-containing system.



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39) Relationship between molecular heat capacity




WHERE :


C(p) = Molecular heat capacity at constant pressure


C(v) = Molecular heat capacity at constant volume


R = Universal gas constant


γ = constant



NOTE: The difference between the molecular heat capacity is equal to the universal gas constant.The ratio between the molecular heat capacity of any gas is constant.



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40) Absolute humidity




WHERE :


A(r) = Absolute humidity


m(v) = Mass of vapor


V = Volume



NOTE: When a space is saturated with water vapor, the maximum absolute humidity is produced at that temperature.



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41) Relative humidity




WHERE :


R(h) = Relative humidity


m = Mass of vapor in a given volume at a given temperature


m(o) = Mass of water vapor required to saturate that volume at that temperature



NOTE : The lateral pressure is equal to the unsaturated vapor pressure.



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42) Relationship with relative humidity and pressure




WHERE :


R(h) = Relative humidity


P = Lateral pressure of water vapor at a given temperature


P(o) = Saturated vapor pressure at that temperature



NOTE : Humidity can be defined in terms of water vapor pressure.


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